![]() Brown, Boranes in Organic Chemistry (Cornell Univ. Tipper (Elsevier Scientific Publishing Co., Amsterdam, 1973).Į. The enthalpies of crystallization of LiNO3 and LiNO33H2O from aqueous solutions at 25☌, measured by a calorimetric method and determined from the previously published data on the concentration dependence of the enthalpy of solution, are reported. 12, Electrophilic Substitution at a Saturated Carbon A tom, ed. Abraham, Comprehensive Chemical Kinetics, vol. Beletskaya, Reaction Mechanisms of Organometallic Compounds (North-Holland Press, Amsterdam, 1968). Rickborn, Electrophilic Substitution of Organomercurials (McGraw-Hill, New York, 1968). Methoden der Organischen Chemie Band XIII/2b Metallorganische Verbindungen: Hg, Georg. Results suggest that multiple radical species are formed during UV photolysis of DMN, perdeutero. Kocheshkov (North-Holland Press, Amsterdam, 1967). Electron nuclear double resonance (ENDOR) spectra of free radicals produced by ultraviolet (UV) photolysis of polycrystalline and single crystal dimethylnitramine (or N-methyl-N-nitromethanamine) DMN (CH 3) 2 NNO 2 were studied at ca. ![]() Nesmeyanov, Methods of Elemento-Organic Chemistry, vol. Whitmore (1921), Organic Compounds of Mercury (Chemical Catalog Company Inc., New York). ![]() This process is experimental and the keywords may be updated as the learning algorithm improves. These keywords were added by machine and not by the authors. The compound 4(Ph 3 SbI) 2 O·I 2 (1) has been obtained by the addition of an I 2 solution in acetonitrile containing ca. Thus reactions of the Hg-X bond in organomercurials of the type RHgX are considered only in as much as they provide a route to new compounds in the same series (RHgY) and to the fully organic mercurials (R 2Hg). Further, in the belief that it is the metal-carbon interaction that is of central interest in organometallic chemistry, our treatment of organomercury reactions is concentrated on those involving the mercury-carbon bond. Thus compounds such as Hg(OPr) 2, Hg(NEt 2) 2 or Hg(SiMe 3) 2 in which mercury is attached to some other atom of an organic moiety are regarded as inorganic mercurials and are not considered here. We have taken the view that organomercury compounds are species in which there is bonding between mercury and organic carbon. There is general agreement as to what constitutes an organic compound, but what is encompassed by the term ‘organometallic’ is more controversial. ![]()
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